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Login to http://account.mylio.com/
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Click "Change Password" below your password.
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Enter the old password and your new password twice, then click "Change Password."
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The next time you open Mylio Photos on any device, use the new password.
Note: Accounts created after March 16, 2023 use Login Links and do not have a password.
Learn More: https://manual.mylio.com/topic/updating-your-account-information